your issue may not be directly related with bufferpool dirty pages~~~ Usually cold bufferpool will making query run slower than warm BP...
anyway, for the specific question you asked "有什么命令可以清除缓冲池数据缓存吗", in the new fixpack (v91fp5+, v95fp2+) there's "db2pdcfg -db <dbname> -flushbp" can be used to flush bufferpool dirty pages